Core-level photoelectron spectroscopy study of the Au/Si(111) 5×2, α-√3×√3, β-√3×√3, and 6×6 surfaces
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OFFPRINT New evidence for the influence of step morphology on the formation of Au atomic chains on vicinal Si(111) surfaces
Gold atomic chain structures that grow on singular and vicinal Si(111) surfaces have attracted considerable interest as model systems for exploring quasi–one-dimensional metallic behaviour. The structure of the prototypical Si(111)-5× 2-Au system remains controversial, however. Reflection anisotropy spectroscopy provides new, independent evidence supporting a recently proposed three-Au-chain st...
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High-resolution soft X-ray photoelectron spectroscopy was used to investigate the oxidation of alkylated silicon(111) surfaces under ambient conditions. Silicon(111) surfaces were functionalized through a two-step route involving radical chlorination of the H-terminated surface followed by alkylation with alkylmagnesium halide reagents. After 24 h in air, surface species representing Si(+), Si(...
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Hydrogen-terminated, chlorine-terminated, and alkyl-terminated crystalline Si(111) surfaces have been characterized using high-resolution, soft X-ray photoelectron spectroscopy from a synchrotron radiation source. The H-terminated Si(111) surface displayed a Si 2p(3/2) peak at a binding energy 0.15 eV higher than the bulk Si 2p(3/2) peak. The integrated area of this shifted peak corresponded to...
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